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CCB
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AC
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Clever
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Research - Clever
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with more than one kind of ligand-centered functionality. We study the interplay of these different chemical modifications, leading to emergent system behavior, control over processes inside the cage cavity [...] ( Li JACS 2019 ). Figure 7: Examples for heteroleptic cages formed by the coordination-sphere engineering approach (left; Zhu CEJ 2018 ) and the shape-complementarity principle (right; Block JACS 2016 [...] cages, featuring coplanar Pd(pyridine) 4 units connected by four banana-shaped ligands of the same chemical structure, to heteroleptic cis -[Pd 2 L 2 L ’ 2 ] cages, having a curved shape, guest binding preference …